Who better to complete “Back-to-School Week,” than the reigning queen B of making school clothing look so good? It’s Blair Waldorf again, sporting an adorable navy blue pencil skirt, white silk blouse, and a matching short tie, complete with a pearl tie tack. Her accessories are what really make the outfit pop – a red belted headband (of course, it’s Blair, after all) with a matching bag, red and white slingbacks, a silk scarf and a layered pearl bracelet. Her true love, Chuck Bass, certainly is her complement in an all-American colored blazer and tie, too. These two certainly make us excited for going back to school!